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Syngas consists primarily of carbon monoxide and hydrogen, and has less than half the energy density of natural gas. It also contains some sulfur compounds, a safety feature since this allows for its detection in the case of leakage. Syngas can be produced from natural gas as follows:
These gasses are combustible, and are often stored to be burned as a fuel source.
For the most part, the amount of synthetic gas produced in a waste to energy facility is only enough to keep the plant operating.
Coal gasification processes[1] (e.g., the water gas process) are reasonably efficient and were used for many years to manufacture illuminating gas (coal gas) for gas lighting, before electric lighting became widely available.
Petroleum