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It lies beneath the Cerro Rico ("Rich mountain"), a mountain of silver ore, which has always dominated the city. Founded 1545 as a mining town, it soon acquired fabulous wealth. In Spanish there is still a saying vale un Potosí meaning "being worth a fortune" and, for Europeans, " Peru" was a mythical land of riches. It is here that most of the Spanish silver came from and Indian labour, forced by Francisco de Toledo through the mita institution, came to die by the thousands. After 1800 the silver mines became depleted, making tin the main product. This eventually led to a slow economic decline.
During the War of Independence (1809-1825) Potosi was frequently passed from the control of Royalist and Patriot forces. Major blunders by the First Argentine Auxilary Army (under the command of Castelli) led to an increased sense that independence was needed and fostered resentment against the Argentine. During that occupation there was anarchy and martial excess, and Potosi became unfriendly to the point where it could not be defended.
When the second auxillary army arrived it was recieved well, and the commander, Belgrano did much to heal the past wounds inflicted by the tyrannical minded Castelli. When that army was forced to retreat, Belgrano took the calculated decision to blow up the Casa de Moneda. Since the locals refused to evacuate this explosion would have resulted in many casualties, but by then the fuse was already lit. Disaster was averted not by the Argentine who at that time were fleeing, but by locals who put the fuse out. In one stroke the good feelings Belgrano delicately built were destroyed. Two more expeditions from the Argentine would seize Potosi.
Zacatecas in Mexico was the other big silver mine of the Spanish Empire.